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--Not only are these my headcanons, but they're also some stuff I changed for my fic (kinda like how comics get retconnned)--
Sci-Twilight: pretty much the same, but she's still nervous since this fic takes place some time after friendship games. She's also a bit jealous of princess Twilight
Princess Twilight: since she's already passed school and stuff, I think she'd be more mature then the cast of equestria girls. (Her crush on EG flash does not exist here. Instead she has a minor crush on Knight flash, but for completely different reasons)
Sunset: this is a big one
In my fic (and also my actual headcanon for canon) Sunset was in her teen years when she left Celestia. When she landed on EG she was still mentally 16-18 but since in EG they get aged down, she became a freshman. So she basically retook highschool all over again, but because her surroundings were still minors and stuff, she didn't grow mentally. Up until 11th grade where her mentality finally matched her physically.
In other words, she stopped growing for a few years
Why this headcanon? Cuz I can't imagine a 30 something year old having a crush on a 17 year old, so this is like twilight,(the vampire movies, not the purple pony) But instead of staying 17 forever and staying at school...for some reason and still kinda growing up because the Cullens do have adults figured, so it's obvious they could've gotten homeschooled at one point to learning mature stuff... Sunset basically paused growing mentally
I know, weird thing to explain
But that's also kind of why I don't exactly ship Princess Twilight with any of the EG girls or boys. She has mentioned her time at highschool, that's a grown ass woman!!