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Steve Rogers had grown up in the 30's, an era of denim and khaki and linen: he knew almost nothing about fabric made of unstable molecules. Clothes were clothes. He felt he was being helpful when he ran several loads of laundry for the team.
The next time the Avengers went into battle, the Hulk exploded through Banner's clothes. All of his clothes. Including his (no longer stretchy) purple pants.
"Hulk FREE!" he roared, swinging his arms along with everything else.
Captain America blanched.
Iron Man facepalmed with an audible 'clank.'
And the hashtag #freeballinghulk started to trend within minutes.