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Roronoa Zoro is a man of simple tastes and pleasures. Great food, good booze, enjoyable company, and a spot to sleep are all it takes to make the swordsman happy on any given day. Recently, the list has grown to include the attentions and affections of a certain raven-haired archaeologist, not that the first mate of the Straw Hats would ever complain about that new addition to his life.
He can spend countless time fighting with Sanji, bettering his skills against the self-proclaimed lovecook as they both let off steam and train to better themselves in support of their Captain.
Nothing quite compares to the time he spends nursing a bottle of booze with Nami, the two taking time to explore one another's past traumas and helping one another move past them in hopes of healing their hearts. He wouldn't admit it, but the navigator is quickly growing into one of his best friends.
His time spent with Luffy is usually focused on ensuring the needs of the crew are met while focusing on the needs of his first friend as well. He wouldn't be a valued first mate if he can't assuage his Captain's fears about protecting the crew.