Adult Content Warning

This work could have adult content. If you continue, you have agreed that you are willing to see such content.

• Yes, Continue
• No, Go Back

If you accept cookies from our site and you choose "Yes, Continue", you will not be asked again during this session (that is, until you close your browser). If you log in you can store your preference and never be asked again.

1. The Scientist, The Witch and the Superspy by Dyrla

   Fandoms: Agents of S.H.I.E.L.D. (TV), Leverage (US TV 2008), Exiles Saga and Galactic Milieu - Julian May, Buffy the Vampire Slayer (TV)  

   • Explicit
   • Graphic Depictions Of Violence, Major Character Death
   • F/F, Gen, F/M, Multi
   • Work in Progress

   05 Oct 2025

   Tags

   • Graphic Depictions Of Violence
   • Major Character Death
   • Faith Lehane/Parker (Leverage)
   • Willow Rosenberg/Jemma Simmons
   • Bobbi Morse/Original Female Character(s)
   • Peggy Carter/Sophie Devereaux (Leverage)
   • Jemma Simmons/Skye | Daisy Johnson
   • Faith Lehane/Parker/Raina
   • jemma simmons/willow rosenberg/skye
   • Natasha Romanov/Original Female Character(s)
   • Willow Rosenberg
   • Jemma Simmons
   • Peggy Carter
   • Faith Lehane
   • Melinda May
   • Parker (Leverage)
   • Nick Fury
   • Rogatien Remillard
   • Original Character Lynette Alvarez
   • Original Character Zafira 'Zee' Merali
   • Sophie Devereaux (Leverage)
   • Bobbi Morse
   • Stephanie Malick
   • Original Character Petra Vasquez
   • Original Characters
   • Madame Vesper
   • Steve Rogers
   • Natasha Romanov
   • Sharon Carter
   • Skye | Daisy Johnson
   • Raina (Agents of S.H.I.E.L.D.)
   • What-If
   • ChatGPT generated
   • Hydra (Marvel)
   • Betrayal
   • Murder
   • Assassination
   • Tragic Romance
   • Polyamory

   Summary

   What if Peggy Carter met Willow Rosenberg at the career fair in the Buffy episode "What's My Line"?

   This fanfic grew from my need to see what a Jemma Simmons & Willow Rosenberg friendship would look like. I thought seeing them interact in Jemma's pre Academy days would be a fun premise.

   Well, that's how it started. It is now an almost 700K word monstrosity with a mission goal and no end in sight!

   I hope you enjoy my ramblings and the darker tones of the later chapters.

   Note: Rated M from chapter 63.

   From Chapter 70ish: This fic contains mature, emotionally intense themes and character death. Please check tags and read responsibly.

   PLEASE READ....... NO I do not want any artwork for this 'on a whim' project. Thank you!

   Series

   • Part 1 of What If...Willow Rosenberg Met Peggy Carter at the Careers Fair

   Language:

   English

   Words:

   898,630

   Chapters:

   109/?

   Comments:

   22

   Kudos:

   16

   Bookmarks:

   5

   Hits:

   1,244